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Enantioselective organocatalytic epoxidation driven by electrochemically generated percarbonate and persulfate


Reference:

Page, P. C. B., Marken, F., Williamson, C., Chan, Y., Buckley, B. R. and Bethell, D., 2008. Enantioselective organocatalytic epoxidation driven by electrochemically generated percarbonate and persulfate. Advanced Synthesis & Catalysis, 350 (7-8), pp. 1149-1154.

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Abstract

An organocatalytic asymmetric epoxidation reaction using iminium salt catalysts is described, in which the stoichiometric persulfate oxidant is generated electrochemically. This system offers comparable ees to the use of commercially available persulfate. Electrochemically generated percarbonate ion is also a successful and novel oxidant system for use with iminium salts.

Details

Item Type Articles
CreatorsPage, P. C. B., Marken, F., Williamson, C., Chan, Y., Buckley, B. R. and Bethell, D.
DOI10.1002/adsc.200800064
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4475
Additional InformationID number: ISI:000255790100028

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