Heterogeneous catalysts for the controlled ring-opening polymerisation of rac-lactide and homogeneous silsesquioxane model complexes

Reference:

Jones, M. D., Davidson, M. G., Keir, C. G., Wooles, A. J., Mahon, M. F. and Apperley, D. C., 2008. Heterogeneous catalysts for the controlled ring-opening polymerisation of rac-lactide and homogeneous silsesquioxane model complexes. Dalton Transactions, 28, pp. 3655-3657.

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Official URL:

http://dx.doi.org/10.1039/b805274c

Abstract

In this communication we report, for the first time, the ring-opening polymerisation in the melt of rac-lactide with heterogeneous catalysts. Homogeneous model systems based on silsesquioxanes have been prepared for comparison.

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