Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)
Reference:
Douglas, T. M., Brayshaw, S. K., Raithby, P. R. and Weller, A. S., 2008. Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2). Inorganic Chemistry, 47 (3), pp. 778-780.
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Abstract
The hydroxyhydrido salt [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) results from the addition of water to [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). This reaction is ;reversible, and the addition of dihydrogen to [Rh-6((PPr3)-Pr-i)(6)H-11(OH)]- [BAr4F](2) results in the elimination of water and the regeneration of the hydride cluster.
Details
| Item Type | Articles |
| Creators | Douglas, T. M., Brayshaw, S. K., Raithby, P. R. and Weller, A. S. |
| DOI | 10.1021/ic702195b |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 4509 |
| Additional Information | ID number: ISI:000252714500007 |
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