Research

Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)


Reference:

Douglas, T. M., Brayshaw, S. K., Raithby, P. R. and Weller, A. S., 2008. Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2). Inorganic Chemistry, 47 (3), pp. 778-780.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below. (Contact Author)

Abstract

The hydroxyhydrido salt [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) results from the addition of water to [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). This reaction is ;reversible, and the addition of dihydrogen to [Rh-6((PPr3)-Pr-i)(6)H-11(OH)]- [BAr4F](2) results in the elimination of water and the regeneration of the hydride cluster.

Details

Item Type Articles
CreatorsDouglas, T. M., Brayshaw, S. K., Raithby, P. R. and Weller, A. S.
DOI10.1021/ic702195b
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4509
Additional InformationID number: ISI:000252714500007

Export

Actions (login required)

View Item