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Highly active and stereoselective zirconium and hafnium alkoxide initiators for solvent-free ring-opening polymerization of rac-lactide


Reference:

Chmura, A. J., Davidson, M. G., Frankis, C. J., Jones, M. D. and Lunn, M. D., 2008. Highly active and stereoselective zirconium and hafnium alkoxide initiators for solvent-free ring-opening polymerization of rac-lactide. Chemical Communications, 2008 (11), pp. 1293-1295.

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Official URL:

http://dx.doi.org/10.1039/b718678a

Abstract

Under solvent-free conditions (at 130 degrees C), zirconium and hafnium amine tris(phenolate) alkoxides are extremely active, well-controlled, single-site initiators for the ring-opening polymerization of rac-lactide, yielding highly heterotactic polylactide.

Details

Item Type Articles
CreatorsChmura, A. J., Davidson, M. G., Frankis, C. J., Jones, M. D. and Lunn, M. D.
DOI10.1039/b718678a
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4513
Additional InformationAn addition/corerction to this paper was published in Chemical Communications Issue 48, 2008, p6611, http://dx.doi.org/10.1039/B819970C ID number: ISI:000254352900007

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