Highly active and stereoselective zirconium and hafnium alkoxide initiators for solvent-free ring-opening polymerization of rac-lactide
Chmura, A. J., Davidson, M. G., Frankis, C. J., Jones, M. D. and Lunn, M. D., 2008. Highly active and stereoselective zirconium and hafnium alkoxide initiators for solvent-free ring-opening polymerization of rac-lactide. Chemical Communications, 2008 (11), pp. 1293-1295.
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Under solvent-free conditions (at 130 degrees C), zirconium and hafnium amine tris(phenolate) alkoxides are extremely active, well-controlled, single-site initiators for the ring-opening polymerization of rac-lactide, yielding highly heterotactic polylactide.
|Creators||Chmura, A. J., Davidson, M. G., Frankis, C. J., Jones, M. D. and Lunn, M. D.|
|Departments||Faculty of Science > Chemistry|
|Additional Information||An addition/corerction to this paper was published in Chemical Communications Issue 48, 2008, p6611, http://dx.doi.org/10.1039/B819970C ID number: ISI:000254352900007|
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