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2,5-Disubstituted furans from 1,4-alkynediols


Reference:

Pridmore, S. J., Slatford, P. A. and Williams, J. M. J., 2007. 2,5-Disubstituted furans from 1,4-alkynediols. Tetrahedron Letters, 48 (29), pp. 5111-5114.

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Abstract

1-4-Alkynediols serve as readily available starting materials for isomerisation to 1,4-diketones, which can be converted in situ into the corresponding furans by acid-catalysed dehydration. A range of 2,5-disubstituted furans was prepared using the ruthenium-based catalyst Ru(PPh3)(3)(CO)H-2 with Xantphos at 1 mol % loading. (C) 2007 Published by Elsevier Ltd.

Details

Item Type Articles
CreatorsPridmore, S. J., Slatford, P. A. and Williams, J. M. J.
DOI10.1016/j.tetlet.2007.05.069
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4549
Additional InformationID number: ISI:000247995900035

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