Ruthenium-catalyzed conversion of 1,4-alkynediols into pyrroles
Pridmore, S. J., Slatford, P. A., Daniel, A., Whittlesey, M. K. and Williams, J. M. J., 2007. Ruthenium-catalyzed conversion of 1,4-alkynediols into pyrroles. Tetrahedron Letters, 48 (29), pp. 5115-5120.
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Various 1,2,5-substituted pyrroles were synthesized from 1,4-alkynediols using a ruthenium-catalyzed isomerization to give the corresponding 1,4-dicarbonyl compds., which undergo in situ cyclization to pyrroles in the presence of amine.
|Creators||Pridmore, S. J., Slatford, P. A., Daniel, A., Whittlesey, M. K. and Williams, J. M. J.|
|Uncontrolled Keywords||glycols role,ketones role,heterocyclization catalysts,isomerization,rct (reactant),cyclization of alkynediols with amines),4-,1,prep (preparation) (diketones,alkynediol amine tandem isomerization heterocyclization ruthenium catalyst,ract (reactant or reagent) (alkynyl,pyrrole prepn,ract (reactant or reagent) (primary,alcohols role,heterocyclization,amines role,cyclization of alkynediols with amines),ract (reactant or reagent) (1,spn (synthetic preparation)|
|Departments||Faculty of Science > Chemistry|
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