A new diastereoselective aza-allyl conjugate addition-Michael addition-ring closure reaction sequence and its application in the construction of six contiguous stereogenic centres
Reference:
Koutsaplis, M., Andrews, P. C., Bull, S. D., Duggan, P. J., Fraser, B. H. and Jensen, P., 2007. A new diastereoselective aza-allyl conjugate addition-Michael addition-ring closure reaction sequence and its application in the construction of six contiguous stereogenic centres. Chemical Communications
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Abstract
Reaction of the sodium anion of (S)-N-(alpha-methylbenzyl)allylamine with two equivalents of tert-butyl cinnamate results in a remarkable tandem aza-allyl conjugate addition-Michael addition-ring closure reaction, resulting in a chiral aminocyclohexane containing six new vicinal stereogenic centres with excellent levels of stereocontrol.
Details
| Item Type | Articles |
| Creators | Koutsaplis, M., Andrews, P. C., Bull, S. D., Duggan, P. J., Fraser, B. H. and Jensen, P. |
| DOI | 10.1039/b707707f |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 4584 |
| Additional Information | ID number: ISI:000249588400028 |
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