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Bis(bismuth) toluene inverted-sandwich complex supported by aminetris(phenoxide) ligands


Reference:

Turner, L. E., Davidson, M. G., Jones, M. D., Ott, H., Schulz, V. S. and Wilson, P. J., 2006. Bis(bismuth) toluene inverted-sandwich complex supported by aminetris(phenoxide) ligands. Inorganic Chemistry, 45 (16), pp. 6123-6125.

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Abstract

The reaction of bismuth amides or alkoxides with phenolic ligand precursors yields Bi complexes of aminetris( phenoxide) s, one of which was characterized by X-ray crystallography, revealing monomeric Bi units of the tetradentate NO3 ligand further associated via a symmetrical toluene bridge into a bis( bismuth) toluene inverted-sandwich complex. Synthesis of the analogous Sb complex suggests a markedly different geometric and electronic environment at the metal center, as evidenced by the solid-state molecular structure. Density functional theory calculations of the sandwich bismuth arene complex indicate the presence of a weak sigma(*)-2 pi interaction.

Details

Item Type Articles
CreatorsTurner, L. E., Davidson, M. G., Jones, M. D., Ott, H., Schulz, V. S. and Wilson, P. J.
DOI10.1021/ic0609406
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4650
Additional InformationID number: ISI:000239394300010

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