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Alkaline- earth-promoted CO homologation and reductive catalysis


Reference:

Anker, M. D., Hill, M. S., Lowe, J. P. and Mahon, M. F., 2015. Alkaline- earth-promoted CO homologation and reductive catalysis. Angewandte Chemie-International Edition, 54 (34), pp. 10009-10011.

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    Official URL:

    http://dx.doi.org/10.1002/anie.201505851

    Abstract

    Reaction between a -diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH3, an observable Mg formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.

    Details

    Item Type Articles
    CreatorsAnker, M. D., Hill, M. S., Lowe, J. P. and Mahon, M. F.
    DOI10.1002/anie.201505851
    DepartmentsFaculty of Science > Chemistry
    Research CentresCentre for Sustainable Chemical Technologies
    RefereedYes
    StatusPublished
    ID Code46598

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