Poly[mu(2)-acetato-diacetonitrile[mu(2)-N,N '-bis(2-hydroxy-phenyl)pyridine-2,6-dicarboxamide]potassium(I)]

Reference:

Perez, Y., Johnson, A. L. and Raithby, P. R., 2006. Poly[mu(2)-acetato-diacetonitrile[mu(2)-N,N '-bis(2-hydroxy-phenyl)pyridine-2,6-dicarboxamide]potassium(I)]. Acta Crystallographica Section E-Structure Reports Online, 62, M2359-M2360.

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Abstract

The title compound, [K(C2H3O2)(C2H3N)(2)(C19H15N3O4)], is polymeric. Each K+ ion adopts a distorted octahedral geometry, being linked to two 2,6-pyridinedicarboxamide ligands through carbonyl O atoms and to two acetate groups also through O atoms. The potassium coordination is completed by the N atoms of two acetonitrile ligands. The 2,6-pyridinedicarboxamide ligands are also involved in O (HO)-O-... hydrogen bonds.

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