Research

Magnesium-catalysed hydroboration of isonitriles


Reference:

Weetman, C., Hill, M. S. and Mahon, M. F., 2015. Magnesium-catalysed hydroboration of isonitriles. Chemical Communications, 51 (77), pp. 14477-14480.

Related documents:

[img]
Preview
PDF (Isonitriles_Comm) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
Download (652kB) | Preview

    Official URL:

    http://dx.doi.org/10.1039/C5CC05708F

    Abstract

    A beta-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.

    Details

    Item Type Articles
    CreatorsWeetman, C., Hill, M. S. and Mahon, M. F.
    DOI10.1039/C5CC05708F
    DepartmentsFaculty of Science > Chemistry
    Research CentresCentre for Sustainable Chemical Technologies
    RefereedYes
    StatusPublished
    ID Code46806

    Export

    Actions (login required)

    View Item

    Document Downloads

    More statistics for this item...