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Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction


Reference:

Creaven, B. S., Mahon, M. F., McGinley, J. and Moore, A. M., 2006. Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction. Inorganic Chemistry Communications, 9 (2), pp. 231-234.

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Abstract

The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom. (c) 2005 Elsevier B.V. All rights reserved.

Details

Item Type Articles
CreatorsCreaven, B. S., Mahon, M. F., McGinley, J. and Moore, A. M.
DOI10.1016/j.inoche.2005.11.008
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4719
Additional InformationID number: ISI:000235269100027

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