Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction
Creaven, B. S., Mahon, M. F., McGinley, J. and Moore, A. M., 2006. Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction. Inorganic Chemistry Communications, 9 (2), pp. 231-234.
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The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom. (c) 2005 Elsevier B.V. All rights reserved.
|Creators||Creaven, B. S., Mahon, M. F., McGinley, J. and Moore, A. M.|
|Departments||Faculty of Science > Chemistry|
|Additional Information||ID number: ISI:000235269100027|
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