An efficient asymmetric synthesis of cascarillic acid
Reference:
Cheeseman, M. and Bull, S. D., 2006. An efficient asymmetric synthesis of cascarillic acid. Synlett
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Abstract
An efficient six-step asymmetric synthesis of the cyclopropane containing natural product cascarillic acid in 41% overall yield is described. The key synthetic steps involve the use of a temporary stereogenic hydroxyl group to control the facial selectivity of a directed cyclopropanation reaction and its subsequent removal via a retro-aldol reaction.
Details
| Item Type | Articles |
| Creators | Cheeseman, M.and Bull, S. D. |
| DOI | 10.1055/s-2006-939690 |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 4724 |
| Additional Information | ID number: ISI:000237436600030 |
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