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An efficient asymmetric synthesis of cascarillic acid


Reference:

Cheeseman, M. and Bull, S. D., 2006. An efficient asymmetric synthesis of cascarillic acid. Synlett

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Abstract

An efficient six-step asymmetric synthesis of the cyclopropane containing natural product cascarillic acid in 41% overall yield is described. The key synthetic steps involve the use of a temporary stereogenic hydroxyl group to control the facial selectivity of a directed cyclopropanation reaction and its subsequent removal via a retro-aldol reaction.

Details

Item Type Articles
CreatorsCheeseman, M.and Bull, S. D.
DOI10.1055/s-2006-939690
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4724
Additional InformationID number: ISI:000237436600030

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