An efficient asymmetric synthesis of cascarillic acid
Cheeseman, M. and Bull, S. D., 2006. An efficient asymmetric synthesis of cascarillic acid. Synlett
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An efficient six-step asymmetric synthesis of the cyclopropane containing natural product cascarillic acid in 41% overall yield is described. The key synthetic steps involve the use of a temporary stereogenic hydroxyl group to control the facial selectivity of a directed cyclopropanation reaction and its subsequent removal via a retro-aldol reaction.
|Creators||Cheeseman, M.and Bull, S. D.|
|Departments||Faculty of Science > Chemistry|
|Additional Information||ID number: ISI:000237436600030|
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