Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)
Reference:
Bowes, K. F., Cole, J. M., Husheer, S. L. G., Raithby, P. R., Savarese, T. L., Sparkes, H. A., Teat, S. J. and Warren, J. E., 2006. Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2). Chemical Communications
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Abstract
The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.
Details
| Item Type | Articles |
| Creators | Bowes, K. F., Cole, J. M., Husheer, S. L. G., Raithby, P. R., Savarese, T. L., Sparkes, H. A., Teat, S. J. and Warren, J. E. |
| DOI | 10.1039/b604039 |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 4739 |
| Additional Information | ID number: ISI:000238101100005 |
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