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Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2)


Reference:

Bowes, K. F., Cole, J. M., Husheer, S. L. G., Raithby, P. R., Savarese, T. L., Sparkes, H. A., Teat, S. J. and Warren, J. E., 2006. Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)(4)(H2O)(eta(1)-OSO)][MeC6H4SO3](2). Chemical Communications

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Abstract

The structure of a new metastable geometric isomer of [Ru(NH3)(4)(H2O)(SO2)][MeC6H4SO3](2) in which the SO2 group is coordinated through a single oxygen in an eta(1)-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.

Details

Item Type Articles
CreatorsBowes, K. F., Cole, J. M., Husheer, S. L. G., Raithby, P. R., Savarese, T. L., Sparkes, H. A., Teat, S. J. and Warren, J. E.
DOI10.1039/b604039
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4739
Additional InformationID number: ISI:000238101100005

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