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Borrowing hydrogen: iridium-catalyzed reactions for the formation of C-C bonds from alcohols


Reference:

Black, P. J., Cami-Kobeci, G., Edwards, M. G., Slatford, P. A., Whittlesey, M. K. and Williams, J. M. J., 2006. Borrowing hydrogen: iridium-catalyzed reactions for the formation of C-C bonds from alcohols. Organic and Biomolecular Chemistry, 4 (1), pp. 116-125.

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Abstract

Alcs. have been employed as substrates for C-C bond-forming reactions which involve initial activation by the temporary removal of hydrogen to form an aldehyde. The intermediate aldehyde is converted into an alkene via a Horner-Wadsworth-Emmons reaction, nitroaldol and aldol reactions. The borrowed hydrogen is then returned to the alkene to form a C-C bond.

Details

Item Type Articles
CreatorsBlack, P. J., Cami-Kobeci, G., Edwards, M. G., Slatford, P. A., Whittlesey, M. K. and Williams, J. M. J.
Uncontrolled Keywordsaddition reaction, ketones role, ract (reactant or reagent) (iridium-catalyzed reactions for formation of c-c bonds from alcs. via intermediate conversion to aldehyde), addition reaction catalysts, ract (reactant or reagent) (nitro, rct (reactant), aldol condensation, horner wadsworth emmons reaction, alc addn nitroalkane phosphonate ketone iridium catalyst, alcohols, aldol condensation catalysts, iridium-catalyzed reactions for formation of c-c bonds from alcs. via intermediate conversion to aldehyde), alkanes role, horner wadsworth emmons reaction catalysts (iridium-catalyzed reactions for formation of c-c bonds from alcs. via intermediate conversion to aldehyde)
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4743

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