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Borrowing hydrogen: iridium-catalyzed reactions for the formation of C-C bonds from alcohols


Reference:

Black, P. J., Cami-Kobeci, G., Edwards, M. G., Slatford, P. A., Whittlesey, M. K. and Williams, J. M. J., 2006. Borrowing hydrogen: iridium-catalyzed reactions for the formation of C-C bonds from alcohols. Organic and Biomolecular Chemistry, 4 (1), pp. 116-125.

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Abstract

Alcs. have been employed as substrates for C-C bond-forming reactions which involve initial activation by the temporary removal of hydrogen to form an aldehyde. The intermediate aldehyde is converted into an alkene via a Horner-Wadsworth-Emmons reaction, nitroaldol and aldol reactions. The borrowed hydrogen is then returned to the alkene to form a C-C bond.

Details

Item Type Articles
CreatorsBlack, P. J., Cami-Kobeci, G., Edwards, M. G., Slatford, P. A., Whittlesey, M. K. and Williams, J. M. J.
Uncontrolled Keywordsaddition reaction,ketones role,ract (reactant or reagent) (iridium-catalyzed reactions for formation of c-c bonds from alcs. via intermediate conversion to aldehyde),addition reaction catalysts,ract (reactant or reagent) (nitro,rct (reactant),aldol condensation,horner wadsworth emmons reaction,alc addn nitroalkane phosphonate ketone iridium catalyst,alcohols,aldol condensation catalysts,iridium-catalyzed reactions for formation of c-c bonds from alcs. via intermediate conversion to aldehyde),alkanes role,horner wadsworth emmons reaction catalysts (iridium-catalyzed reactions for formation of c-c bonds from alcs. via intermediate conversion to aldehyde)
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4743

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