Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand
Reference:
Andrews, C. D., Burrows, A. D., Green, M., Lynam, J. M. and Mahon, M. F., 2006. Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand. Journal of Organometallic Chemistry, 691 (13), pp. 2859-2862.
Related documents:
This repository does not currently have the full-text of this item.You may be able to access a copy if URLs are provided below.
Abstract
The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.
Details
| Item Type | Articles |
| Creators | Andrews, C. D., Burrows, A. D., Green, M., Lynam, J. M. and Mahon, M. F. |
| DOI | 10.1016/j.jorganchem.2006.03.014 |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 4744 |
| Additional Information | ID number: ISI:000238309200001 |
Export
Actions (login required)
| View Item |
