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Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand


Reference:

Andrews, C. D., Burrows, A. D., Green, M., Lynam, J. M. and Mahon, M. F., 2006. Transformation of an eta(1)-coordinated phosphaalkyne into a bridging phosphinidene ligand. Journal of Organometallic Chemistry, 691 (13), pp. 2859-2862.

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Abstract

The tripalladium cluster [Pd-3( mu(3)-CO)( mu-dppm)(3)](PF6)(2) (1) reacts with two equivalents of (BuCP)-Bu-t to give [Pd-3(mu-dppm)(3)(eta(1)-PCBut)(2)](PF6)(2) (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd-3(mu-dppm)(3)(eta(1):mu(3)-PCH2But)(OCMC2)](PF6)(2) (3). Compound 3 has been characterized by X-ray crystallography. (c) 2006 Elsevier B.V. All rights reserved.

Details

Item Type Articles
CreatorsAndrews, C. D., Burrows, A. D., Green, M., Lynam, J. M. and Mahon, M. F.
DOI10.1016/j.jorganchem.2006.03.014
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4744
Additional InformationID number: ISI:000238309200001

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