Electrolyte free electro-organic synthesis: The cathodic dimerisation of 4-nitrobenzylbromide in a micro-gap flow cell
He, P., Watts, P., Marken, F. and Haswell, S. J., 2005. Electrolyte free electro-organic synthesis: The cathodic dimerisation of 4-nitrobenzylbromide in a micro-gap flow cell. Electrochemistry Communications, 7 (9), pp. 918-924.
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The electrochemical reduction of 4-nitrobenzylbromide is studied in NN-dimethylformamide solution in the presence and in the absence of intentionally added supporting electrolyte. By conventional voltammetry it is shown that an ECE-type reaction occurs with formation of the dimer 4,4'-dinitrodibenzyl irrespective of the presence of supporting electrolyte. Next, a micro-gap flow cell is characterised and employed for the preparative electro-reduction in the absence of supporting electrolyte. Excellent yields of the dimer are obtained and explained based on a self-propagation mechanism. (c) 2005 Elsevier B.V. All rights reserved.
|Creators||He, P., Watts, P., Marken, F. and Haswell, S. J.|
|Departments||Faculty of Science > Chemistry|
|Additional Information||ID number: ISI:000231591000009|
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