Research

Reactions of bis(tetrazole)phenylenes. Surprising formation of vinyl compounds from alkyl halides


Reference:

Fleming, A., Kelleher, F., Mahon, M. F., McGinley, J. and Prajapati, V., 2005. Reactions of bis(tetrazole)phenylenes. Surprising formation of vinyl compounds from alkyl halides. Tetrahedron, 61 (29), pp. 7002-7011.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below.

Abstract

The reactions of 1,2-bis(tetrazol-5-yl)benzene (1), 1,3-bis(tetrazol-5-yl)benzene (2), 1,4-bis(tetrazol-5-yl)benzene (3), 1,2(Bu3SnN4C)(2)C6H4 (4), 1,3-(Bu(3)SnN(4)Q(2)C(6)H(4) (5) and 1,4-(Bu3SnN4C)(2)C6H4 (6) with 1,2-dibromoethane were carried out by two different methods in order to synthesise pendant alkyl halide derivatives of the parent bis-tetrazoles. This lead to the formation of several alkyl halide derivatives, substituted at either N1 or N2 on the tetrazole ring, as well as the surprising formation of several vinyl derivatives. The crystal structures of both 1,2-1(2- vinyl)tetrazol-5-yl)] benzene (1-N.2-N') (1b) and 1,3-bis[(2-bromoethyl)tetrazol-5-yl]benzene (2-N,2-N) (5d) are discussed. (c) 2005 Elsevier Ltd. All rights reserved.

Details

Item Type Articles
CreatorsFleming, A., Kelleher, F., Mahon, M. F., McGinley, J. and Prajapati, V.
DOI10.1016/j.tet.2005.05.013
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4813
Additional InformationID number: ISI:000230146400009

Export

Actions (login required)

View Item