Diaquabis(1,1,4-trimethylthiosemicarbazide)-nickel(II) dinitrate

Reference:

Burrows, A. D., Harrington, R. W. and Mahon, M. F., 2005. Diaquabis(1,1,4-trimethylthiosemicarbazide)-nickel(II) dinitrate. Acta Crystallographica Section E-Structure Reports Online, 61, M551-M553.

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Abstract

The determination of the crystal structure of the title compound, [Ni(C4H11N3S)(2)(H2O)(2)](NO3)(2), reveals a distorted octahedral geometry around the Ni centre, which lies on an inversion centre, with water molecules occupying the axial positions. Hydrogen bonding is observed between the 1,1,4-trimethylthiosenticarbazide NH groups and the nitrate anions, and also between the coordinated water molecules and the anions.

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