Direct and transfer hydrogenation of ketones and imines with a ruthenium N-heterocyclic carbene complex
Burling, S., Whittlesey, M. K. and Williams, J. M. J., 2005. Direct and transfer hydrogenation of ketones and imines with a ruthenium N-heterocyclic carbene complex. Advanced Synthesis & Catalysis, 347 (4), pp. 591-594.
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The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes)(PPh3)2CO(H)2 (IMes = 1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.
|Creators||Burling, S., Whittlesey, M. K. and Williams, J. M. J.|
|Uncontrolled Keywords||ketones role, imines and alkenes), imines, hydrogenation (alc. oxidn., rct (reactant), alc. oxidn., alcohols, ruthenium nitrogen heterocyclic carbene complex catalyzed hydrogenation, ketone and imine redn. via ruthenium n-heterocyclic carbene complex catalyzed direct and transfer hydrogenation between alcs., hydrogenation (transfer, ract (reactant or reagent) (alc. oxidn., alc oxidn ketone imine redn direct transfer hydrogenation, ketones|
|Departments||Faculty of Science > Chemistry|
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