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Direct and transfer hydrogenation of ketones and imines with a ruthenium N-heterocyclic carbene complex


Reference:

Burling, S., Whittlesey, M. K. and Williams, J. M. J., 2005. Direct and transfer hydrogenation of ketones and imines with a ruthenium N-heterocyclic carbene complex. Advanced Synthesis & Catalysis, 347 (4), pp. 591-594.

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Abstract

The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes)(PPh3)2CO(H)2 (IMes = 1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.

Details

Item Type Articles
CreatorsBurling, S., Whittlesey, M. K. and Williams, J. M. J.
Uncontrolled Keywordsketones role, imines and alkenes), imines, hydrogenation (alc. oxidn., rct (reactant), alc. oxidn., alcohols, ruthenium nitrogen heterocyclic carbene complex catalyzed hydrogenation, ketone and imine redn. via ruthenium n-heterocyclic carbene complex catalyzed direct and transfer hydrogenation between alcs., hydrogenation (transfer, ract (reactant or reagent) (alc. oxidn., alc oxidn ketone imine redn direct transfer hydrogenation, ketones
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4837

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