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Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster


Reference:

Thapper, A., Sparr, E., Johnson, B. F. G., Lewis, J., Raithby, P. R. and Nordlander, E., 2004. Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster. Inorganic Chemistry Communications, 7 (3), pp. 443-446.

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Abstract

The triallylphosphine-substituted clusters [Ru-3(CO)(10){P(CH2CH=CH2)(3)}], [Ru-3(CO)(10){P(CH2CH=CH2)(3)}(2)] and [Ru-3(CO)(10) {sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] have been prepared; reaction of [Ru-3(CO)(10){sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11){P(CH2CH=CH2)(3)}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.

Details

Item Type Articles
CreatorsThapper, A., Sparr, E., Johnson, B. F. G., Lewis, J., Raithby, P. R. and Nordlander, E.
DOI10.1016/j.inoche.2003.12.032
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4861
Additional InformationID number: ISI:000189229800037

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