Research

Effects of diphosphine structure on aurophilicity and luminescence in Au(I) complexes


Reference:

Pintado-Alba, A., de la Riva, H., Nieuwhuyzen, M., Bautista, D., Raithby, P. R., Sparkes, H. A., Teat, S. J., Lopez-de-Luzuriaga, J. M. and Lagunas, M. C., 2004. Effects of diphosphine structure on aurophilicity and luminescence in Au(I) complexes. Dalton Transactions

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below.

Abstract

The effects of diphosphine flexibility and bite angle on the structures and luminescence properties of Au(I) complexes have been investigated. A range of diphosphines based on heteroaromatic backbones [ bis(2-diphenylphosphino) phenylether (dpephos), 9,9-dimethyl-4,5-bis(diphenylphosphino) xanthene (xantphos), and 4,6-bis(diphenylphosphino) dibenzofuran (dbfphos)] has been used to prepare mono- and digold derivatives. A clear relationship between the presence of aurophilic contacts and the emission properties of dinuclear complexes has been observed, with one of the complexes studied, [Au2Cl2(mu-xantphos)], exhibiting luminescence thermochromism.

Details

Item Type Articles
CreatorsPintado-Alba, A., de la Riva, H., Nieuwhuyzen, M., Bautista, D., Raithby, P. R., Sparkes, H. A., Teat, S. J., Lopez-de-Luzuriaga, J. M. and Lagunas, M. C.
DOI10.1039/b410619a
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4879
Additional InformationID number: ISI:000224735600011

Export

Actions (login required)

View Item