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trans-(mu-5,5 '-diethynyl-2,2 '-bipyridine)bis-[phenylbis(triethylphosphine)platinum(II)]


Reference:

Khan, M. S., Al-Suti, M. K., Ahrens, B., Raithby, P. R. and Teat, S. J., 2004. trans-(mu-5,5 '-diethynyl-2,2 '-bipyridine)bis-[phenylbis(triethylphosphine)platinum(II)]. Acta Crystallographica Section E-Structure Reports Online, 60, M735-M737.

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Abstract

The title compound, [Pt-2(C6H5)(2)(C14H6N2)(C6H15P)(4)], is a dinuclear Pt-II di-yne complex that exhibits pi-conjugation along the molecular backbone. It is used as a model complex for rigid-rod platinum poly-yne polymers of which it is a precursor. Such compounds are of interest because of the extended pi-conjugation through the aromatic/heteroaromatic spacer group in the backbone. The asymmetric unit contains two half molecules of the title compound, each lying on a crystallographic centre of symmetry situated at the mid-point of the central C - C bond of the bipyridine unit.

Details

Item Type Articles
CreatorsKhan, M. S., Al-Suti, M. K., Ahrens, B., Raithby, P. R. and Teat, S. J.
DOI10.1107/s1600536804010359
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4896
Additional InformationID number: ISI:000222371200014

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