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[PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation


Reference:

Ingleson, M. J., Mahon, M. F. and Weller, A. S., 2004. [PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation. Chemical Communications

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Abstract

The T-shaped Pt(II) complex [PtMe((Pr3P)-Pr-i)(2)][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)((Pr3P)-Pr-i)((Pr2PCHMeCH2)-Pr-i)][1-H-closo-CB11Me11].

Details

Item Type Articles
CreatorsIngleson, M. J., Mahon, M. F. and Weller, A. S.
DOI10.1039/b410846a
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4908
Additional InformationID number: ISI:000224755600013

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