[PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation
Reference:
Ingleson, M. J., Mahon, M. F. and Weller, A. S., 2004. [PtMe(iPr3P)(2)](+): a Pt(II) complex with an agostic interaction that undergoes C-H activation. Chemical Communications
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Abstract
The T-shaped Pt(II) complex [PtMe((Pr3P)-Pr-i)(2)][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)((Pr3P)-Pr-i)((Pr2PCHMeCH2)-Pr-i)][1-H-closo-CB11Me11].
Details
| Item Type | Articles |
| Creators | Ingleson, M. J., Mahon, M. F. and Weller, A. S. |
| DOI | 10.1039/b410846a |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 4908 |
| Additional Information | ID number: ISI:000224755600013 |
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