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A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2 center dot THF center dot TMEDA](2) and [(C6H11)PS3Mg center dot 2THF](2)


Reference:

Bjernemose, J. K., Davies, R. P., Jurd, A. P. S., Martinelli, M. G., Raithby, P. R. and White, A. J. P., 2004. A new synthetic route to metal trithiophosphonates: Syntheses and structures of [(C6H11)PS3Li2 center dot THF center dot TMEDA](2) and [(C6H11)PS3Mg center dot 2THF](2). Dalton Transactions

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Abstract

A new synthesis for trithiophosphonates from primary phosphines, nBuLi (or nBu(2)Mg) and elemental sulfur is presented and its mechanism investigated; the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.

Details

Item Type Articles
CreatorsBjernemose, J. K., Davies, R. P., Jurd, A. P. S., Martinelli, M. G., Raithby, P. R. and White, A. J. P.
DOI10.1039/b412488j
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4951
Additional InformationID number: ISI:000224462300004

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