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Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]


Reference:

Rifat, A., Mahon, M. F. and Weller, A. S., 2003. Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]. Journal of Organometallic Chemistry, 667 (1-2), pp. 1-4.

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Abstract

Treatment of the arene bridged dimer [(PPh3)(2)Rh](2)[closo-CB11H6Br6](2) with eight equivalents of cyclohexene affords [(eta(4)- C6H8)Rh(PPh3)(2)][closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. (C) 2002 Elsevier Science B.V. All rights reserved.

Details

Item Type Articles
CreatorsRifat, A., Mahon, M. F. and Weller, A. S.
DOI10.1016/s0022-328x(02)01923-x
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4966
Additional InformationID number: ISI:000181147000001

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