Khan, M. S., Al-Suti, M. K., Mahon, M. F., Male, L. and Raithby, P. R., 2003. trans-mu-(2,5-dioctyl-1,4-phenylene)diethynylbis[phenylbis(triethylphosp hine)platinum(II)]. Acta Crystallographica Section E-Structure Reports Online, 59, M833-M835.
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The title compound, [Pt-2(C6H5)(2)(C26H36)(C6H15P)(4)], is a dinuclear Pt-II di-yne compound exhibiting pi-conjugation along the molecular backbone. It is used as a model species for rigid-rod platinum poly-yne compounds of which it is a precursor. Such compounds are of interest due to the extended pi-conjugation through the aromatic linker unit in the backbone. In this structure, the molecule lies on an inversion centre such that the asymmetric unit comprises half the formula unit.
|Creators||Khan, M. S., Al-Suti, M. K., Mahon, M. F., Male, L. and Raithby, P. R.|
|Departments||Faculty of Science > Chemistry|
|Additional Information||ID number: ISI:000185644100004|
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