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trans-mu-(2,5-dioctyl-1,4-phenylene)diethynylbis[phenylbis(triethylphosp hine)platinum(II)]


Reference:

Khan, M. S., Al-Suti, M. K., Mahon, M. F., Male, L. and Raithby, P. R., 2003. trans-mu-(2,5-dioctyl-1,4-phenylene)diethynylbis[phenylbis(triethylphosp hine)platinum(II)]. Acta Crystallographica Section E-Structure Reports Online, 59, M833-M835.

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Abstract

The title compound, [Pt-2(C6H5)(2)(C26H36)(C6H15P)(4)], is a dinuclear Pt-II di-yne compound exhibiting pi-conjugation along the molecular backbone. It is used as a model species for rigid-rod platinum poly-yne compounds of which it is a precursor. Such compounds are of interest due to the extended pi-conjugation through the aromatic linker unit in the backbone. In this structure, the molecule lies on an inversion centre such that the asymmetric unit comprises half the formula unit.

Details

Item Type Articles
CreatorsKhan, M. S., Al-Suti, M. K., Mahon, M. F., Male, L. and Raithby, P. R.
DOI10.1107/s1600536803018889
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code4993
Additional InformationID number: ISI:000185644100004

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