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(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate


Reference:

Jones, M. D., Paz, F. A. A., Davies, J. E., Johnson, B. F. G. and Klinowski, J., 2003. (eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate. Acta Crystallographica Section E-Structure Reports Online, 59, M538-M540.

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Abstract

The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.

Details

Item Type Articles
CreatorsJones, M. D., Paz, F. A. A., Davies, J. E., Johnson, B. F. G. and Klinowski, J.
DOI10.1107/s1600536803012741
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5000
Additional InformationID number: ISI:000183875000060

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