(eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate
Reference:
Jones, M. D., Paz, F. A. A., Davies, J. E., Johnson, B. F. G. and Klinowski, J., 2003. (eta(3)-Allyl)[(R)-(+)-2,2 '-bis(diphenylphosphino)-1,1 '-binaphthyllpalladium(II) trifluoromethanesulfonate dichloromethane solvate. Acta Crystallographica Section E-Structure Reports Online, 59, M538-M540.
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Abstract
The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3).CH2Cl2, has been determined at 180 (2) K in the non-centrosymmetric space group P2(1)2(1)2(1). The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.
Details
| Item Type | Articles |
| Creators | Jones, M. D., Paz, F. A. A., Davies, J. E., Johnson, B. F. G. and Klinowski, J. |
| DOI | 10.1107/s1600536803012741 |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 5000 |
| Additional Information | ID number: ISI:000183875000060 |
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