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A new polymorph of [(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2,N '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate


Reference:

Jones, M. D., Paz, F. A. A., Davies, J. E., Johnson, B. F. G. and Klinowski, J., 2003. A new polymorph of [(S)-(-)-2-aminomethyl-1-ethylpyrrolidine-kappa N-2,N '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate. Acta Crystallographica Section E-Structure Reports Online, 59, M1091-M1093.

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Abstract

The structure of a new polymorph of the title compound, [Rh(C8H12)(C7H16N2)]CF3SO3, the first form of which we recently reported [Rouzaud et al. (2003). Helv. Chim. Acta, 86, 1753-1759], has been determined at 180 K in space group C222(1). The differences between the two polymorphs, are related to the way the individual ions close-pack within the unit cell.

Details

Item Type Articles
CreatorsJones, M. D., Paz, F. A. A., Davies, J. E., Johnson, B. F. G. and Klinowski, J.
DOI10.1107/s1600536803024760
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5002
Additional InformationID number: ISI:000186886200007

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