[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate
Reference:
Jones, M. D., Paz, F. A. A., Davies, J. E. and Johnson, B. F. G., 2003. [1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate. Acta Crystallographica Section E-Structure Reports Online, 59, M111-M113.
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Abstract
The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.
Details
| Item Type | Articles |
| Creators | Jones, M. D., Paz, F. A. A., Davies, J. E. and Johnson, B. F. G. |
| DOI | 10.1107/s1600536803003581 |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 5004 |
| Additional Information | ID number: ISI:000181609600014 |
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