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[1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate


Reference:

Jones, M. D., Paz, F. A. A., Davies, J. E. and Johnson, B. F. G., 2003. [1,1 '-bis(diphenylphosphino)ferrocene-kappa P-2,P '](1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate dichloromethane disolvate. Acta Crystallographica Section E-Structure Reports Online, 59, M111-M113.

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Abstract

The title compound, [Rh(C8H12)(C34H28P2Fe)]CF3SO3.2CH(2)Cl(2) or [RhFe(C8H12)(C17H14P)(2)]CF3SO3.2CH(2)Cl(2), was synthesized by reacting 1,1'-bis(diphenylphosphino)ferrocene (dppf) with [Rh(1,5-cyclooctadiene)(THF)(2)](+) in tetrahydrofuran (THF), and shows dppf acting as a P,P'-bidentate chelating ligand. The compound crystallizes in the space group P2(1)/n and features one crystallographically unique Rh+ metal centre, which appears in a distorted square-planar geometry.

Details

Item Type Articles
CreatorsJones, M. D., Paz, F. A. A., Davies, J. E. and Johnson, B. F. G.
DOI10.1107/s1600536803003581
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5004
Additional InformationID number: ISI:000181609600014

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