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(eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate


Reference:

Jones, M. D., Paz, F. A. A., Davies, J. E. and Johnson, B. F. G., 2003. (eta(3)-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate. Acta Crystallographica Section E-Structure Reports Online, 59, M105-M107.

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Abstract

The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

Details

Item Type Articles
CreatorsJones, M. D., Paz, F. A. A., Davies, J. E. and Johnson, B. F. G.
DOI10.1107/s600536803003507
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5005
Additional InformationID number: ISI:000181609600012

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