Research

Some tricyclohexyltin carboxylates containing germanium: synthesis, spectral and crystallographic characterization


Reference:

Imtiaz ud, D., Molloy, K. C., Mazhar, M., Dastgir, S., Ali, S. and Mahon, M. F., 2003. Some tricyclohexyltin carboxylates containing germanium: synthesis, spectral and crystallographic characterization. Applied Organometallic Chemistry, 17 (10), pp. 781-787.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below.

Abstract

Six tricyclohexyltin triorganogermyl (substituted) propionates have been synthesized and their structures characterized by IR, multinuclear magnetic resonance (H-1, C-13, Sn-119) and Mossbauer spectroscopies. Three of them have been characterized crystallographically by X-ray diffraction. The crystal structures of [(p-CH3C6H4)(3)GeCH(p-CH3C6H4)CH2COOSn(C6H11)(3)] (1) and [(C6H5)(3)GeCH(C6H5)CH(CH3)COOSn(C6H11)(3)] (3) indicate that the tin possesses a tetrahedral geometry. The crystal structure of [(p-CH3C6H4)(3)GeCH(p-CH3OC6H4)CH2COOSn(C6H11)(3)]H2O (2) shows trigonal bipyramidal geometry around the tin with water of hydration enhancing the coordination sphere of the metal. Some of these compounds demonstrated positive antibacterial, antifungal and lethality bioassays. Copyright (C) 2003 John Wiley Sons, Ltd.

Details

Item Type Articles
CreatorsImtiaz ud, D., Molloy, K. C., Mazhar, M., Dastgir, S., Ali, S. and Mahon, M. F.
DOI10.1002/aoc.504
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5015
Additional InformationID number: ISI:000185705000005

Export

Actions (login required)

View Item