Enantiomerically pure nucleophiles in diastereoselective palladium catalysed allylic substitution reactions
Reference:
Humphries, M. E., Clark, B. P., Regini, S., Acemoglu, L. and Williams, J. M. J., 2003. Enantiomerically pure nucleophiles in diastereoselective palladium catalysed allylic substitution reactions. Chirality, 15 (2), pp. 190-195.
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Abstract
Enantiomerically pure alpha-amino esters were applied in palladium catalysed allylic substitution reactions with moderate diastereoselectivity (up to 70% d.e.) using achiral ligands on symmetrical allylic acetates. Nucleophilic substitution of amino esters with enantiomerically pure ligands enabled diastereoselective ratios of 95:5 to be obtained.
Details
| Item Type | Articles |
| Creators | Humphries, M. E., Clark, B. P., Regini, S., Acemoglu, L. and Williams, J. M. J. |
| DOI | 10.1002/chir.10173 |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 5017 |
| Additional Information | ID number: ISI:000180696800013 |
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