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Enantiomerically pure nucleophiles in diastereoselective palladium catalysed allylic substitution reactions


Reference:

Humphries, M. E., Clark, B. P., Regini, S., Acemoglu, L. and Williams, J. M. J., 2003. Enantiomerically pure nucleophiles in diastereoselective palladium catalysed allylic substitution reactions. Chirality, 15 (2), pp. 190-195.

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Abstract

Enantiomerically pure alpha-amino esters were applied in palladium catalysed allylic substitution reactions with moderate diastereoselectivity (up to 70% d.e.) using achiral ligands on symmetrical allylic acetates. Nucleophilic substitution of amino esters with enantiomerically pure ligands enabled diastereoselective ratios of 95:5 to be obtained.

Details

Item Type Articles
CreatorsHumphries, M. E., Clark, B. P., Regini, S., Acemoglu, L. and Williams, J. M. J.
DOI10.1002/chir.10173
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5017
Additional InformationID number: ISI:000180696800013

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