An (E)-selective synthesis of trisubstituted (E)-alpha,beta-unsaturated acid derivatives

Reference:

Feuillet, F. J. P., Robinson, D. and Bull, S. D., 2003. An (E)-selective synthesis of trisubstituted (E)-alpha,beta-unsaturated acid derivatives. Chemical Communications

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Abstract

Potassium alkoxides of N-acyloxazolidin-2-one derived syn-aldolates undergo a novel tandem intramolecular cyclisation elimination reaction to afford trisubstituted( E)-alpha,beta-unsaturated amides in high d.e., which may be converted into their corresponding acids or oxazolines in good yield.

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