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Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex


Reference:

Chatwin, S. L., Diggle, R. A., Jazzar, R. F. R., MacGregor, S. A., Mahon, M. F. and Whittlesey, M. K., 2003. Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex. Inorganic Chemistry, 42 (24), pp. 7695-7697.

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Abstract

Addn. of 1 atm. of H2S to [Ru(IMes)2(CO)(EtOH)H2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)2(CO)(H2S)H2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes)2(CO)(SH)2] 3. Preliminary studies show that 3 reacts with both H2 and CO in soln. as well as in the solid state. Both 2 and 3 have been structurally characterized.

Details

Item Type Articles
CreatorsChatwin, S. L., Diggle, R. A., Jazzar, R. F. R., MacGregor, S. A., Mahon, M. F. and Whittlesey, M. K.
Uncontrolled Keywordshydrosulfido ruthenium imidazolylidene thiol complex prepn crystal mol structure, molecular mechanics (prepn., reactivity, structure, and computational studies of ruthenium hydrogen sulfide dihydride complex), prepn., density functional theory, molecular structure (of imidazolylidene ruthenium hydrogen sulfide dihydride and bis-hydrosulfido complexes), crystal structure, molecular structure (optimized, imidazolylidene ruthenium hydrogen sulfide dihydride complex prepn crystal structure
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5048

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