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Disorder within dicarboxylates and supramolecular structural control in hydrogen-bonded networks


Reference:

Burke, N. J., Burrows, A. D., Mahon, M. F. and Pritchard, L. S., 2003. Disorder within dicarboxylates and supramolecular structural control in hydrogen-bonded networks. CrystEngComm, 5, pp. 355-357.

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Abstract

The crystal structures of two hydrogen-bonded adducts containing omicron-bromoterephthalate have been determined and shown to be virtually identical to those of their terephthalate analogues. Consequently, the strategy of manipulating the relative orientation of the carboxylate groups by adding a bromine atom to terephthalate, which has previously been used to give metal-organic frameworks with predictable structure, can be frustrated with the observation of disorder in the bromine position.

Details

Item Type Articles
CreatorsBurke, N. J., Burrows, A. D., Mahon, M. F. and Pritchard, L. S.
DOI10.1039/b309884b
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5062
Additional InformationID number: ISI:000185630700001

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