Disorder within dicarboxylates and supramolecular structural control in hydrogen-bonded networks

Reference:

Burke, N. J., Burrows, A. D., Mahon, M. F. and Pritchard, L. S., 2003. Disorder within dicarboxylates and supramolecular structural control in hydrogen-bonded networks. CrystEngComm, 5, pp. 355-357.

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Abstract

The crystal structures of two hydrogen-bonded adducts containing omicron-bromoterephthalate have been determined and shown to be virtually identical to those of their terephthalate analogues. Consequently, the strategy of manipulating the relative orientation of the carboxylate groups by adding a bromine atom to terephthalate, which has previously been used to give metal-organic frameworks with predictable structure, can be frustrated with the observation of disorder in the bromine position.

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