Synthesis, structure and catalytic activity of an air-stable titanium triflate, supported by an amine tris(phenolate) ligand

Reference:

Bull, S. D., Davidson, M. G., Johnson, A. L., Robinson, D. and Mahon, M. F., 2003. Synthesis, structure and catalytic activity of an air-stable titanium triflate, supported by an amine tris(phenolate) ligand. Chemical Communications

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Abstract

An air- and moisture-stable titanium(IV) triflate, 3, supported by a C-3-symmetric amine tris( phenolate) ligand has been synthesised, characterised by X-ray crystallography and demonstrated to be an excellent catalyst for formal aza-Diels - Alder reactions.

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