Research

Structures of Sb(OC6H3Me2-2,6)(3) and Sb(OEt)(5)center dot NH3: The first authenticated monomeric Sb(OR)(n) (n=3, 5)


Reference:

Horley, G. A., Mahon, M. F., Molloy, K. C., Venter, M. M., Haycock, P. W. and Myers, C. P., 2002. Structures of Sb(OC6H3Me2-2,6)(3) and Sb(OEt)(5)center dot NH3: The first authenticated monomeric Sb(OR)(n) (n=3, 5). Inorganic Chemistry, 41 (6), pp. 1652-1657.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below.

Abstract

The first monomeric antimony alkoxides, Sb(OC6H3Me2)(3) (1) and Sb(OEt)(5).NH3 (2), have been crystallographically characterized. The former adopts a trigonal pyramidal geometry, while the latter is octahedral about antimony; hydrogen bonding between NH3 and SbOEt groups in Sb(OEt)(5).NH3 creates a one-dimensional lattice arrangement. Reaction of pyridine with SbCl5 in EtOH/hexane yields the salt [Hpy(+)](9)[Sb2Cl115-][Cl-](4) (3), which has also been crystallographically characterized. Crystallographic data: 1, C24H27O3Sb, a = 10.9080(2), b = 11.9660(2), c = 17-7260(4) Angstrom, alpha = 109.740(1)degrees, monoclinic P2(1)/c (unique axis a), Z = 4; 2, C10H28NO5Sb, a = 7.7220(l), b = 19.0700(2), c = 21.6800(3) Angstrom, 93.4960(7)degrees, monoclinic P2(1)/c, Z = 8; 3, C45H54Cl15N9Sb2, a 13.4300(2), b = 14.4180(2), c = 17.4180(3) Angstrom, alpha = 82.7650(7), beta = 77.5570(7), gamma = 70.7670(7)degrees, triclinic Z = 2.

Details

Item Type Articles
CreatorsHorley, G. A., Mahon, M. F., Molloy, K. C., Venter, M. M., Haycock, P. W. and Myers, C. P.
DOI10.1021/ic0106726
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5133
Additional InformationID number: ISI:000174492300042

Export

Actions (login required)

View Item