Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate

Reference:

Diop, C. A. K., Bassene, S., Sidibe, M., Sarr, A. D., Diop, L., Molloy, K. C., Mahon, M. F. and Toscano, R. A., 2002. Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate. Main Group Metal Chemistry, 25 (11), pp. 683-689.

Related documents:

Abstract

The crystal and spectroscopic characterization of three triorganotin derivatives, namely [Ph3SnO3SPh](n), [Me3SnO2P(OH)(Me)](n) and [Me3SnO2As(OH)(Ph)](n) are reported. In each case the structure consists of one- or three-dimensional, polymeric chains involving R3Sn (R = Me, Ph) moieties axially bridged through either benzenesulphonato, methylphosphonato or phenylarsonato ligands. The tin atoms in each case are in a trans-O2SnC3 trigonal bipyramidal environment. Hydrogen bonds ensure the compactness of the structures of the methylphosphonato and phenylarsonato derivatives.

Export

Actions (login required)