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Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate


Reference:

Diop, C. A. K., Bassene, S., Sidibe, M., Sarr, A. D., Diop, L., Molloy, K. C., Mahon, M. F. and Toscano, R. A., 2002. Synthesis, characterization and X-ray structures of catena triphenyltin(IV) benzenesulphonate, catena-trimethyltin(IV) methylphosphonate and catena-trimethyltin(IV) phenylarsenate. Main Group Metal Chemistry, 25 (11), pp. 683-689.

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Abstract

The crystal and spectroscopic characterization of three triorganotin derivatives, namely [Ph3SnO3SPh](n), [Me3SnO2P(OH)(Me)](n) and [Me3SnO2As(OH)(Ph)](n) are reported. In each case the structure consists of one- or three-dimensional, polymeric chains involving R3Sn (R = Me, Ph) moieties axially bridged through either benzenesulphonato, methylphosphonato or phenylarsonato ligands. The tin atoms in each case are in a trans-O2SnC3 trigonal bipyramidal environment. Hydrogen bonds ensure the compactness of the structures of the methylphosphonato and phenylarsonato derivatives.

Details

Item Type Articles
CreatorsDiop, C. A. K., Bassene, S., Sidibe, M., Sarr, A. D., Diop, L., Molloy, K. C., Mahon, M. F. and Toscano, R. A.
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5146
Additional InformationID number: ISI:000179594200007

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