Research

Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands


Reference:

Thorpe, T., Blacker, J., Brown, S. M., Bubert, C., Crosby, J., Fitzjohn, S., Muxworthy, J. P. and Williams, J. M. J., 2001. Efficient rhodium and iridium-catalysed asymmetric transfer hydrogenation using water-soluble aminosulfonamide ligands. Tetrahedron Letters, 42 (24), pp. 4041-4043.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below.

Abstract

A range of aromatic ketones was reduced asymmetrically under transfer hydrogenation conditions using enantiomerically pure catalysts derived from water-soluble diamine ligands and [Cp*MCl2](2) (Cp* = pentamethylcyclopentadienyl, M = Rh, Ir). High catalytic activity and enantioselectivity were observed in systems containing up to 51% water. (C) 2001 Elsevier Science Ltd. All rights reserved.

Details

Item Type Articles
CreatorsThorpe, T., Blacker, J., Brown, S. M., Bubert, C., Crosby, J., Fitzjohn, S., Muxworthy, J. P. and Williams, J. M. J.
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5185
Additional InformationID number: ISI:000169116400021

Export

Actions (login required)

View Item