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Evidence for alpha-lactone intermediates in addition of aqueous bromine to disodium dimethyl-maleate and -fumarate


Reference:

Robinson, J. J., Buchanan, J. G., Charlton, M. H., Kinsman, R. G., Mahon, M. F. and Williams, I. H., 2001. Evidence for alpha-lactone intermediates in addition of aqueous bromine to disodium dimethyl-maleate and -fumarate. Chemical Communications

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Abstract

Crystallographic analysis of the bromo-beta -lactones obtained by addition of bromine to aqueous solutions of disodium 2,3-dimethylmaleate and 2,3-dimethylfumarate reveals stereochemistries opposite to those originally assigned and suggests that the first-formed intermediate in each case is an alpha -lactone.

Details

Item Type Articles
CreatorsRobinson, J. J., Buchanan, J. G., Charlton, M. H., Kinsman, R. G., Mahon, M. F. and Williams, I. H.
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5189
Additional InformationID number: ISI:000167149600045

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