C-F bond activation of perfluoroalkenes by ruthenium phosphine hydride complexes: x-ray crystal structures of cis-Ru(dmpe)2F(F.HF) and [Ru(dcpe)2H]+[(CF3)2C:C(O)CF2CF3]
Reference:
Kirkham, M. S., Mahon, M. F. and Whittlesey, M. K., 2001. C-F bond activation of perfluoroalkenes by ruthenium phosphine hydride complexes: x-ray crystal structures of cis-Ru(dmpe)2F(F.HF) and [Ru(dcpe)2H]+[(CF3)2C:C(O)CF2CF3]. Chemical Communications
Related documents:
This repository does not currently have the full-text of this item.You may be able to access a copy if URLs are provided below.
Abstract
The reaction of (CF3)2C:C(F)CF2CF3 or CF3CF:CF2 with cis-Ru(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) affords the bifluoride fluoride complex cis-Ru(dmpe)2F(F.HF), whereas reaction with Ru(dcpe)2H2 (dcpe = (C6H11)2PCH2CH2P(C6H11)2) yields [Ru(dcpe)2H]+ with [(CF3)2C:C(O)CF2CF3]- as the anion. Thus the pathways for C-F bond activation of the perfluoroalkenes by Ru(P-P)2H2 are highly dependent upon the phosphine substituents. Cis-Ru(dmpe)2F(F.HF) and [Ru(dcpe)2H][(CF3)2C:C(O)CF2CF3] were characterized by x-ray crystallog.
Details
| Item Type | Articles |
| Creators | Kirkham, M. S., Mahon, M. F. and Whittlesey, M. K. |
| Uncontrolled Keywords | ruthenium diphosphine fluoride bifluoride hydride prepn structure, crystal structure ruthenium diphosphine fluoride bifluoride hydride, crystal structure, perfluoroalkene carbon fluorine bond activation ruthenium diphosphine hydride complex, bond cleavage (carbon-fluorine, molecular structure (of ruthenium bis(dimethylphosphino)ethane bifluoride fluoride and bis(dicyclohexylphosphino)ethane hydride complexes), carbon-fluorine bond activation of perfluoroalkenes by ruthenium diphosphinoethane hydride complexes) |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 5202 |
Export
Actions (login required)
| View Item |
