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Synthesis and spectral characterisation of organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes, including the crystal structures of 1,3,5-(R3Sn)(3)C3N3S3 (R = Me, Ph)


Reference:

Haiduc, I., Mahon, M. F., Molloy, K. C. and Venter, M. M., 2001. Synthesis and spectral characterisation of organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes, including the crystal structures of 1,3,5-(R3Sn)(3)C3N3S3 (R = Me, Ph). Journal of Organometallic Chemistry, 627 (1), pp. 6-12.

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Abstract

Novel organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes: (R3Sn)(3)C3N3S3, (R = Ph, Bz, Me, Bu) and (R2Sn)(3)(C3N3S3)(2), (R = Ph, Me) have been prepared and characterised by elemental analysis, FT-IR, Mossbauer and multinuclear NMR spectroscopy. The crystal and molecular structures of 1,3,5-(R3Sn)(3)C3N3S3 (R = Me, Ph) have been determined and contain tetrahedral organotin units in a 'manxane' arrangement about the central triazine. There are no close intermolecular interactions. (C) 2001 Elsevier Science B.V. All rights reserved.

Details

Item Type Articles
CreatorsHaiduc, I., Mahon, M. F., Molloy, K. C. and Venter, M. M.
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5221
Additional InformationID number: ISI:000168607700002

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