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The bis(eta-cyclopentadienyl)titanium(IV) - salicylate system revisited and the characterisation of two 3,5-di-t-butylsalicylate analogues. The molecular structure of [Cp2Ti(sal)], (sal = O2CC6H4O2-)


Reference:

Edwards, D. A., Mahon, M. F., Paget, T. J. and Summerhill, N. W., 2001. The bis(eta-cyclopentadienyl)titanium(IV) - salicylate system revisited and the characterisation of two 3,5-di-t-butylsalicylate analogues. The molecular structure of [Cp2Ti(sal)], (sal = O2CC6H4O2-). Transition Metal Chemistry, 26 (1-2), pp. 116-119.

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Abstract

The Cp2TiIV - salicylate system has been re-examined and procedures for the syntheses of [Cp2Ti(salH)(2)] and [Cp2Ti(sal)] explored, [salH = (O2CC6H4OH-2)(-); sal = (O2CC6H4O-2)(2-)]. The new 3,5-di-t-butylsalicylate analogues have been prepared and characterised. An X-ray structure determination of [Cp2Ti(sal)] confirms the chelating nature of the sal ligand which is bonded to the metal through the phenolic and one of the carboxylate oxygen atoms.

Details

Item Type Articles
CreatorsEdwards, D. A., Mahon, M. F., Paget, T. J. and Summerhill, N. W.
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code5225
Additional InformationID number: ISI:000165089500021

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