Research

Aerosol-Assisted chemical vapor deposition of cds from xanthate single source precursors


Reference:

Buckingham, M. A., Catherall, A. L., Hill, M. S., Johnson, A. L. and Parish, J. D., 2017. Aerosol-Assisted chemical vapor deposition of cds from xanthate single source precursors. Crystal Growth and Design, 17 (2), pp. 907-912.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below. (Contact Author)

Official URL:

http://dx.doi.org/10.1021/acs.cgd.6b01795

Related URLs:

Abstract

Bis-3-methylpyridine and bis-4-methylpyridine complexes of cadmium(II) ethylxanthate have been characterized by elemental analysis, NMR spectroscopy, and thermogravimetric analysis. The single crystal X-ray structures of both methylpyridine derivatives have also been determined and shown to display a cis, cis, cis-configuration of the N-And S-donor ligands. The compounds have been utilized as single source precursors to deposit CdS films on silica-coated glass substrates at 220 and 350 °C by aerosol-Assisted chemical vapor deposition. The surface morphology of the films has been examined by scanning electron microscopy analysis and the crystalline phases were studied by powder X-ray diffraction. The films deposited from the 3-methylpyridine adduct comprised more densely packed and more highly crystalline hexagonal CdS than those provided by either of the other two precursors. The crystallite sizes were found to be g = 2.25-2.40 eV) consistent with bulk CdS.

Details

Item Type Articles
CreatorsBuckingham, M. A., Catherall, A. L., Hill, M. S., Johnson, A. L. and Parish, J. D.
DOI10.1021/acs.cgd.6b01795
Related URLs
URLURL Type
http://www.scopus.com/inward/record.url?scp=85011320117&partnerID=8YFLogxKUNSPECIFIED
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code54709

Export

Actions (login required)

View Item