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Ring expansion of a ring expanded carbene


Reference:

Garcia Rodriguez, L., Al Fahraiji, K., Wilson, D. J. D., Dutton, J., Hill, M. and Mahon, M., 2017. Ring expansion of a ring expanded carbene. Dalton Transactions, 46 (36), pp. 12015-12018.

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Official URL:

http://dx.doi/10.1039/C7DT03046K

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Abstract

Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.

Details

Item Type Articles
CreatorsGarcia Rodriguez, L., Al Fahraiji, K., Wilson, D. J. D., Dutton, J., Hill, M. and Mahon, M.
DOI10.1039/c7dt03046k
Related URLs
URLURL Type
http://doi.org/10.1039/C7DT03046KFree Full-text
DepartmentsFaculty of Science > Chemistry
Research CentresCentre for Sustainable Chemical Technologies
RefereedYes
StatusPublished
ID Code57911

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