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A tetrameric lithiated phosphazene containing a lithium atom bound exclusively to four sp(3)-hybridized carbanionic centers: A key intermediate for understanding structure-reactivity relationships of phosphazenyllithium compounds


Reference:

Gomez, G. R., Fernandez, I., Ortiz, F. L., Price, R. D., Davidson, M. G., Mahon, M. F. and Howard, J. A. K., 2007. A tetrameric lithiated phosphazene containing a lithium atom bound exclusively to four sp(3)-hybridized carbanionic centers: A key intermediate for understanding structure-reactivity relationships of phosphazenyllithium compounds. Organometallics, 26 (3), pp. 514-518.

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http://dx.doi.org/10.1021/om0608354

Abstract

The structure of the first tetrameric alpha-lithiated N-phenylphosphazene has been determined in the solid state and shown to persist in toluene solution, an observation that gives insight into the variation in stereoselectivity found for reactions of alpha-lithiated phosphazenes with aldehydes.

Details

Item Type Articles
CreatorsGomez, G. R., Fernandez, I., Ortiz, F. L., Price, R. D., Davidson, M. G., Mahon, M. F. and Howard, J. A. K.
DOI10.1021/om0608354
DepartmentsFaculty of Science > Pharmacy & Pharmacology
Faculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code7621
Additional InformationID number: ISI:000243577000011

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