A tetrameric lithiated phosphazene containing a lithium atom bound exclusively to four sp(3)-hybridized carbanionic centers: A key intermediate for understanding structure-reactivity relationships of phosphazenyllithium compounds

Reference:

Gomez, G. R., Fernandez, I., Ortiz, F. L., Price, R. D., Davidson, M. G., Mahon, M. F. and Howard, J. A. K., 2007. A tetrameric lithiated phosphazene containing a lithium atom bound exclusively to four sp(3)-hybridized carbanionic centers: A key intermediate for understanding structure-reactivity relationships of phosphazenyllithium compounds. Organometallics, 26 (3), pp. 514-518.

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Official URL:

http://dx.doi.org/10.1021/om0608354

Abstract

The structure of the first tetrameric alpha-lithiated N-phenylphosphazene has been determined in the solid state and shown to persist in toluene solution, an observation that gives insight into the variation in stereoselectivity found for reactions of alpha-lithiated phosphazenes with aldehydes.

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