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The first mixed-anion complex of a lithium phosphazene: Synthesis and crystal and solution structure of [(LiCH2P(Ph)(2)=NPh)center dot(LiOC6H2-2,6-{C(CH3)(3)}-4-CH3)](2)


Reference:

Price, R. D., Fernandez, I., Gomez, G. R., Ortiz, F. L., Davidson, M. G., Cowan, J. A. and Howard, J. A. K., 2004. The first mixed-anion complex of a lithium phosphazene: Synthesis and crystal and solution structure of [(LiCH2P(Ph)(2)=NPh)center dot(LiOC6H2-2,6-{C(CH3)(3)}-4-CH3)](2). Organometallics, 23 (25), pp. 5934-5938.

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Abstract

The crystal and toluene solution structure (X-ray, H-1, Li-7, C-13, P-31 NMR) of a mixed-anion lithium phosphazene-phenolate, 10, is a six-rung ladder consisting of two LiPCN units fused to a central Li2O2 core, which provides insight into the function of phosphazenyl-stabilized carbanions as reagents. The mixed aggregate showed decreased reactivity toward benzaldehyde with respect to the uncomplexed anion.

Details

Item Type Articles
CreatorsPrice, R. D., Fernandez, I., Gomez, G. R., Ortiz, F. L., Davidson, M. G., Cowan, J. A. and Howard, J. A. K.
DOI10.1021/om049608x
DepartmentsFaculty of Science > Pharmacy & Pharmacology
RefereedYes
StatusPublished
ID Code8020
Additional InformationID number: ISI:000225456000012

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